【单选题】
[1]在同样的条件下,用标样代替试样进行的平行测定叫作___。
A. 空白实验
B. 对照实验
C. 回收实验
D. 校正实验
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答案
B
解析
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【单选题】
[2]带有玻璃活塞的滴定管常用来装___。
A. 见光易分解的溶液
B. 酸性溶液
C. 碱性溶液
D. 任何溶液
【单选题】
[3]天平零点相差较小时,可调节___。
A. 指针
B. 拔杆
C. 感量螺钉
D. 吊耳
【单选题】
[3]使用电光分析天平时,取放物体时要托起横梁是为了___。
A. 减少称量时间
B. 保护玛瑙刀口
C. 保护横梁
D. 便于取放物体
【单选题】
[2]BpH=5.26中的有效数字是___位。
A. 0
B. 2
C. 3
D. ,4
【单选题】
[2]下列有关置信区间的定义中,正确的是___。
A. 以真值为中心的某一区间包括测定结果的平均值的概率
B. 在一定置信度时,以测量值的平均值为中心的,包括真值在内的可靠范围
C. 总体平均值与测定结果的平均值相等的概率
D. 在一定置信度时,以真值为中心的可靠范围
【单选题】
[3]要准确量取25.00mL的稀盐酸,可用的量器是___。
A. 25ml的量筒
B. 25ml的酸式滴定管
C. 25mL的碱式滴定管
D. 25mL的烧杯
【单选题】
[2]用电光天平称量时,天平的零点为-0.3mg,肖砝码和环码加到11.3500g时,天平停点为+4.5mg。此物重为___。
A. 11.3545g
B. 11.3548g
C. 11.3542g
D. 11.0545g
【单选题】
[2]下述论述中错误的是___。
A. 方法误差属于系统误差
B. 系统误差包括操作误差
C. 系统误差呈现正态分布
D. 系统误差具有单向性
【单选题】
[3]如果要求分析结果达到0.1%的准确度,使用灵敏度为0.1mg的天平称量时,至少要取___。
A. 0.lg
B. 0.05g
C. 0.2g
D. 0.5g
【单选题】
[1]下列关于平行测定结果准确度与精密度的描述正确的有___。
A. 精密度高则没有随机误差
B. 精密度高则准确度一定高
C. 精密度高表明方法的重现性好
D. 存在系统误差则精密度一定不高
【单选题】
[2]NaHCO3纯度的技术指标为≥99.0%,下列测定结果不符合要求的是___。
A. 0.9905
B. 0.9901
C. 0.9894
D. 0.9895
【单选题】
[3]定量分析工作要求测定结果的误差___
A. 越小越好
B. 等于零
C. 在允许误差范围之内
D. 略大于允许误差
【单选题】
[2]算式(30.582-7.44)+(1.6-0.5263)中,绝对误差最大的数据是___。
A. 30.582
B. 7.44
C. 1.6
D. 0.5263
【单选题】
[1]制备的标准溶液浓度与规定浓度相对误差不得大于___。
A. 0.01
B. 0.02
C. 0.05
D. 0.l
【单选题】
[3]相对误差的计算公式是___。
A. E(%)=真实值-绝对误差
B. E(%)=绝对误差-真实值
C. E(%)=(绝对误差/真实值)×100%
D. E(%)=(真实值/绝对误差)×100%
【单选题】
[2]1.34×10-3%有效数字是___位。
A. 6
B. 5
C. 3
D. 8
【单选题】
[2]由计算器算得2.236×1.1124÷1.036×0.2000的结果为12.004471,按有效数字运算规则应将结果修约为___。
A. 12
B. 12.0
C. 12.00
D. 12.004
【单选题】
[2]将1245修约为三位有效数字,正确的是___。
A. 1240
B. 1250
C. 1.24×103
D. 1.25×103
【单选题】
[2]下列四个数据中修改为四位有效数字后为0.0624的是___。(1)0.56235;(2)0.562349;(3)0.56245;(4)0.562451。
A. (1),(2)
B. (3),(4)
C. (1),(3)
D. (2),(4)
【单选题】
[2]下列容量瓶的使用不正确的是___。
A. 使用前应检查是否漏水
B. 瓶塞与瓶应配套使用
C. 使用前在烘箱中烘干
D. 容量瓶不宜代替试剂瓶使用
【单选题】
[2]在22℃时,用已洗净的25mL移液管,准确移取25.00mL纯水,置于已准确称量过的50mL的锥形瓶中,称得水的质量为24.9613g,此移液管在20℃时的真实体积为___。22℃时水的密度为0.99680g/mL。
A. 25.00mL
B. 24.96mL
C. 25.04mL
D. 25.02
【单选题】
[1]进行移液管和容量瓶的相对校正对___。
A. 移液管和容量瓶的内壁都必须绝对干燥
B. 移液管和容量瓶的内壁都不必干燥
C. 容量瓶的内壁必须绝对干燥,移液管内壁可以不干燥
D. 容量瓶的内壁可以不干燥,移液管内壁必须绝对干燥
【单选题】
[2]关于天平砝码的取用方法,正确的是___。
A. 戴上手套用手取
B. 拿纸条夹取
C. 用镊子夹取
D. 直接用手取
【单选题】
[1]在一组平行测定中,测得试样中钙的质量分数分别为22.38、22.37、22.36、22.40、22.48,用Q检验判断、应弃去的是___。( 已知:Q0.90=0.64,n=5)
A. 22.38
B. 22.4
C. 22.48
D. 22.36
【单选题】
[2]某煤中水分含量在5%至10%之间时,规定平行测定结果的允许绝对偏差不大于0.3%,对某一煤实验进行3次平行测定,其结果分别为7.17%、7.31%及7.72%,应弃去的是___,
A. 0.0772
B. 0.0717
C. 7.72%
D. 0.0731
【单选题】
[3]进行中和滴定时,事先不应该用所盛溶液润洗的仪器是___。
A. 酸式滴定管
B. 碱式滴定管
C. 锥形瓶
D. 移液管
【单选题】
[3]使分析天平较快停止摆动的部件是___。
A. 吊耳
B. 指针
C. 阻尼器
D. 平衡螺丝
【单选题】
[2]在滴定分析法测定中出现的下列情况,___属于系统误差。
A. 试样未经充分混匀
B. 滴定管的读数读错
C. 滴定时有液滴溅出
D. 砝码未经校正
【单选题】
[2]对某试样进行对照测定,获得其中硫的平均含量为3.25%,则其中某个测定值与此平均值之差为该测定的___。
A. 绝对误差
B. 相对误差
C. 相对偏差
D. 绝对偏差
【单选题】
[2]下列数据记录有错误的是___。
A. 分析天平0.2800g
B. 移液管25.00ml
C. 滴定管25.00ml
D. 量筒25.00ml
【单选题】
[3]欲测某水泥熟料中的SO2含量,由四人分别进行测定。试样称取量皆为2.2g,四人获得四份报告如下:0.020852、0.02085、0.0208、2.1%,其中合理的报告是___。
A. 0.020802
B. 0.02085
C. 0.0208
D. 2.1%
【单选题】
[2]洌定SO2的质量分数,得到下列数据___:28.62,28.59,28.51,28.52,28.61。则置信度为95%时平均值的置信区间为。(已知置信度为95%,n=5,t=2.776)
A. 28.57±0.12
B. 28.57±0.13
C. 28.56±0.13
D. 28.57±0.06
【单选题】
[2]要改变分析天平的灵敏度可调节___。
A. 吊耳
B. 平衡螺钉
C. 拔杆
D. 感量螺钉
【单选题】
[2]衡量样本平均值的离散程庋时,应采用___。
A. 标准偏差
B. 相对标准偏差
C. 极差
D. 平均值的标准偏差
【单选题】
[2]当置信度为0.95时,测得Al2O3的μ置信区间为(35.21±0.10)%,其意义是___。
A. 在所测定的数据中有95%在此区间内
B. 若再进行测定,将有95%的数据落人此区间内
C. 一总体平均值μ落入此区间的概率为0.95
D. 在此区间内包含μ值的概率为0.95
【单选题】
[2]由计算器计算9.25×0.21334÷(1.200×100)的结果为0.0164449,按有效数字规则将结果修约为___。
A. 0.016445
B. 0.01645
C. 0.01644
D. 0.0164
【单选题】
[2] 16℃时1mL水的质量为0.99780g,在此温度下校正l0ml单标线移液管,称得其放出的纯水质量为10.04g,此移液管在20℃时的校正值是___。
A. -0.02 mL
B. +0.02 mL
C. -0.06 mL
D. +0.06 mL
【判断题】
[2]容量瓶与移液管不配套会引起偶然误差
A. 对
B. 错
【判断题】
[2]在没有系统误差的前提条件下,总体平均值就是真实值
A. 对
B. 错
【判断题】
[3]准确度表示分析结果与真实值接近的程度。它们之间的差别越大,则准确度越高
A. 对
B. 错
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